What is the enthalpy of formation of $NH_3$ if the bond enthalpies are $(N \equiv N) = 941 \ kJ/mol$,$(H-H) = 436 \ kJ/mol$,and $(N-H) = 389 \ kJ/mol$?

  • A
    $-84.5 \ kJ/mol$
  • B
    $-21.25 \ kJ/mol$
  • C
    $-42.5 \ kJ/mol$
  • D
    $-63.45 \ kJ/mol$

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Given that,$C_{(s)} + O_{2(g)} \longrightarrow CO_{2(g)} ; \Delta H^{\circ} = -x \ kJ \ mol^{-1}$ and $2CO_{(g)} + O_{2(g)} \longrightarrow 2CO_{2(g)} ; \Delta H^{\circ} = -y \ kJ \ mol^{-1}$. The enthalpy of formation of $CO$ will be:

The standard enthalpy of formation $(\Delta_fH^o)$ at $298 \ K$ for methane,$CH_{4(g)}$ is $-74.8 \ kJ \ mol^{-1}$. The additional information required to determine the average energy for $C-H$ bond formation would be

Consider the following reactions:
$(i)$ $H_{(aq)}^{+} + OH^{-}_{(aq)} \longrightarrow H_2O_{(l)}$,$\Delta H = -X_1 \ kJ \ mol^{-1}$
$(ii)$ $H_{2_{(g)}} + \frac{1}{2} O_{2_{(g)}} \longrightarrow H_2O_{(l)}$,$\Delta H = -X_2 \ kJ \ mol^{-1}$
$(iii)$ $CO_{2_{(g)}} + H_{2_{(g)}} \longrightarrow CO_{(g)} + H_2O_{(l)}$,$\Delta H = -X_3 \ kJ \ mol^{-1}$
$(iv)$ $C_2H_{2_{(g)}} + \frac{5}{2} O_{2_{(g)}} \longrightarrow 2CO_{2_{(g)}} + H_2O_{(l)}$,$\Delta H = -X_4 \ kJ \ mol^{-1}$
Enthalpy of formation of $H_2O_{(l)}$ is

If at $298 \, K$ the bond energies of $C-H, C-C, C=C$ and $H-H$ bonds are respectively $414, 347, 615$ and $435 \, kJ \, mol^{-1}$,the value of enthalpy change for the reaction $H_2C=CH_{2(g)} + H_{2(g)} \to H_3C-CH_{3(g)}$ at $298 \, K$ will be $.... \, kJ$.

The $\Delta H_f^o$ for $CO_{2(g)}$,$CO_{(g)}$ and $H_2O_{(g)}$ are $-393.5$,$-110.5$ and $-241.8 \ kJ \ mol^{-1}$ respectively. The standard enthalpy change (in $kJ$) for the reaction $CO_{2(g)} + H_{2(g)} \to CO_{(g)} + H_2O_{(g)}$ is

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