What is the product formed in the following r | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(B) The reaction of phenol with carbon tetrachloride $(CCl_4)$ in the presence of aqueous sodium hydroxide $(NaOH)$ is known as the Reimer-Tiemann rea

Vedclass · Accepted Answer

$o-$hydroxybenzoic acid

Vedclass · Answer

(B) The reaction of phenol with carbon tetrachloride $(CCl_4)$ in the presence of aqueous sodium hydroxide $(NaOH)$ is known as the Reimer-Tiemann reaction (using $CCl_4$ variant).This reaction introduces a carboxylic acid group $( -COOH )$ at the ortho position of the phenol ring.Initially,the phenoxide ion reacts with the dichlorocarbene intermediate (generated from $CCl_4$ and $NaOH$) to form an ortho-substituted intermediate,which upon hydrolysis and acidification $(H^+)$ yields $o-$hydroxybenzoic acid (also known as salicylic acid).Therefore,the correct product is $o-$hydroxybenzoic acid.

What is the product formed in the following reaction?
$C_6H_5OH + CCl_4 \xrightarrow[(2) \ H^{+}]{(1) \ NaOH}$

Similar Questions

Which of the following phenols is isolated from the defensive secretion of grasshopper species?

In the above sequence of reactions,the major products $X$ and $Y$ are

The major product of the following reaction is:

$Phenol$ $\xrightarrow[Distillation]{Zn} A$ $\xrightarrow[Conc. H_2SO_4]{Conc. HNO_3} B$ $\xrightarrow[NaOH]{Zn} C$
In the above reaction,$A$,$B$,and $C$ are the following compounds:

The rate of electrophilic substitution reaction in phenol is:

Vedclass Test Series

Exam Paper Generator

Online Exam Module

What is the product formed in the following reaction?$C_6H_5OH + CCl_4 \xrightarrow[(2) \ H^{+}]{(1) \ NaOH}$