When $20 \ g$ of $CaCO_3$ are subjected to decomposition at $227 \ ^oC$ in a closed container of $10 \ L$ capacity,$50 \%$ of $CaCO_3$ remained unreacted at equilibrium. Calculate $K_P$ for $CaCO_{3(s)} \rightleftharpoons CaO_{(s)} + CO_{2(g)}$ in $atm$.

  • A
    $0.41$
  • B
    $0.72$
  • C
    $0.80$
  • D
    $0.27$

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In a one-litre flask,$6$ moles of $A$ undergoes the reaction $A_{(g)} \rightleftharpoons P_{(g)}$. The progress of product formation at two temperatures (in Kelvin),$T_1$ and $T_2$,is shown in the figure:
If $T_1=2 T_2$ and $(\Delta G_2^{\Theta}-\Delta G_1^{\Theta})=R T_2 \ln x$,then the value of $x$ is. . . . .
$[\Delta G_1^{\Theta}$ and $\Delta G_2^{\Theta}$ are standard Gibb's free energy change for the reaction at temperatures $T_1$ and $T_2$,respectively.]

For the reaction $N_2 + 3H_2 \rightleftharpoons 2NH_3$,what is the relationship between $\Delta H$ and $\Delta E$?

Solid $NH_4HS$ is placed in a flask containing $NH_3$ gas at a certain temperature and a pressure of $0.50 \ atm$. The $NH_4HS$ decomposes to form $NH_3$ gas and $H_2S$ gas. When equilibrium is established in the flask,the total pressure increases to $0.84 \ atm$. What is the equilibrium constant $(K_p)$ for the decomposition of $NH_4HS$ at this temperature?

Observe the following equations:
$Ag^{+} + NH_3 \rightleftharpoons [Ag(NH_3)]^{+}$,$K_1 = 1.6 \times 10^3$
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The equilibrium constant for the following reaction,$Ag^{+} + 2 NH_3 \rightleftharpoons [Ag(NH_3)_2]^{+}$ is

$A$ gaseous reaction $A_{2(g)} \to B_{(g)} + \frac{1}{2} C_{(g)}$ shows an increase in pressure from $100 \ mm$ of $Hg$ to $120 \ mm$ of $Hg$ in $5 \ min$. What will be the rate of disappearance of $A_2$ in $mm$ of $Hg/min$?

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