When $BCl_3$ is treated with water,it hydrolyses and forms $[B(OH)_4]^-$ only,whereas $AlCl_3$ in acidified aqueous solution forms $[Al(H_2O)_6]^{3+}$ ion. Explain what are the hybridizations of boron and aluminum in these species?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) In the trivalent state,most compounds are covalent and undergo hydrolysis in water. For example,trichlorides on hydrolysis in water form tetrahedral $[M(OH)_4]^-$ species; the hybridization state of element $M$ is $sp^3$.
$BCl_3 + 3H_2O \rightarrow B(OH)_3 + 3HCl$
$B(OH)_3 + H_2O \rightarrow [B(OH)_4]^- + H^+$
In $[B(OH)_4]^-$,boron is $sp^3$ hybridized.
Aluminum chloride in acidified aqueous solution forms the octahedral $[Al(H_2O)_6]^{3+}$ ion. In this complex ion,the $3d$-orbitals of $Al$ are involved and the hybridization state of $Al$ is $sp^3d^2$.
$AlCl_3 + 6H_2O \xrightarrow{HCl} [Al(H_2O)_6]^{3+} + 3Cl^-$

Explore More

Similar Questions

Describe the change in hybridisation (if any) of the $Al$ atom in the following reaction.
$AlCl_{3} + Cl^{-} \longrightarrow AlCl_{4}^{-}$

Which of the following compounds has $sp^2$ hybridization?

Consider the following reaction: $MX_4 + X'_2 \to MX_4X'_2$. If the atomic number of $M$ is $52$ and $X$ and $X'$ are halogens and $X'$ is more electronegative than $X$. Then choose the correct statement regarding the given information.

$XeF_4$ is square planar whereas $CCl_4$ is tetrahedral because

$sp^3d^2$ hybridization is not displayed by

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo