When a metal rod $M$ is dipped into an aqueous colourless concentrated solution of compound $N$,the solution turns light blue. Addition of aqueous $NaCl$ to the blue solution gives a white precipitate $O$. Addition of aqueous $NH_3$ dissolves $O$ and gives an intense blue solution.
$1.$ The metal rod $M$ is
$(A)$ $Fe$ $(B)$ $Cu$ $(C)$ $Ni$ $(D)$ $Co$
$2.$ The compound $N$ is
$(A)$ $AgNO_3$ $(B)$ $Zn(NO_3)_2$
$(C)$ $Al(NO_3)_3$ $(D)$ $Pb(NO_3)_2$
$3.$ The final solution contains
$(A)$ $[Pb(NH_3)_4]^{2+}$ and $[CoCl_4]^{2-}$
$(B)$ $[Al(NH_3)_4]^{3+}$ and $[Cu(NH_3)_4]^{2+}$
$(C)$ $[Ag(NH_3)_2]^{+}$ and $[Cu(NH_3)_4]^{2+}$
$(D)$ $[Ag(NH_3)_2]^{+}$ and $[Ni(NH_3)_6]^{2+}$
Give the answer for questions $1$,$2$ and $3$.

  • A
    $(B, A, C)$
  • B
    $(A, B, C)$
  • C
    $(A, B, D)$
  • D
    $(B, C, D)$

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Which of the following statements is correct?

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For the given aqueous reaction,which of the statement$(s)$ is (are) true?
$2KI + 2K_3[Fe(CN)_6] \xrightarrow{H_2SO_4} I_2 + 2K_4[Fe(CN)_6]$
$(A)$ The first reaction is a redox reaction.
$(B)$ White precipitate is $K_2Zn_3[Fe(CN)_6]_2$.
$(C)$ Addition of filtrate to starch solution gives blue colour.
$(D)$ White precipitate is soluble in $NaOH$ solution.

Consider the following reaction and identify the correct statement:
$[M(gly)_2(NH_3)_2]^+ \xrightarrow[-2NH_3]{+gly} [M(gly)_3]$

Match the complexes in Column-$I$ with their properties listed in Column-$II$.
Column-$I$ Column-$II$
$A$. $[Co(NH_3)_4(H_2O)_2]Cl_2$ $p$. geometrical isomers
$B$. $[Pt(NH_3)_2Cl_2]$ $q$. paramagnetic
$C$. $[Co(H_2O)_5Cl]Cl$ $r$. diamagnetic
$D$. $[Ni(H_2O)_6]Cl_2$ $s$. metal ion with $+2$ oxidation state

In basic medium, the amount of $Ni^{2+}$ in a solution can be estimated with the dimethylglyoxime reagent. The correct statement$(s)$ about the reaction and the product is (are):

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