When phenol reacts with ammonia in the presen | vedclass

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Question

(A) The reaction of phenol with ammonia in the presence of anhydrous $ZnCl_2$ at $300 \ ^oC$ is known as the Bucherer reaction or a variation of the a

Vedclass · Accepted Answer

Primary amine

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(A) The reaction of phenol with ammonia in the presence of anhydrous $ZnCl_2$ at $300 \ ^oC$ is known as the Bucherer reaction or a variation of the ammonolysis of phenols.In this reaction,the hydroxyl group $(-OH)$ of phenol is replaced by an amino group $(-NH_2)$ to form aniline.$C_6H_5OH + NH_3 \xrightarrow{ZnCl_2, 300 \ ^oC} C_6H_5NH_2 + H_2O$Aniline $(C_6H_5NH_2)$ is a primary amine because the nitrogen atom is attached to only one carbon atom of the benzene ring.Therefore,the correct option is $A$.

When phenol reacts with ammonia in the presence of $ZnCl_2$ at $300 \ ^oC$,it gives:

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