When propene reacts with HCl in the presence | vedclass

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(C) The reaction of $HCl$ with an unsymmetrical alkene like propene follows Markovnikov's rule,even in the presence of peroxide. Peroxide effect (Khar

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$2-$chloropropane

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(C) The reaction of $HCl$ with an unsymmetrical alkene like propene follows Markovnikov's rule,even in the presence of peroxide. Peroxide effect (Kharasch effect) is only applicable to $HBr$ and not to $HCl$ or $HI$. According to Markovnikov's rule,the negative part of the reagent $(Cl^-)$ attaches to the carbon atom with fewer hydrogen atoms. Thus,$CH_3-CH=CH_2 + HCl \rightarrow CH_3-CHCl-CH_3$ ($2-$chloropropane).

When propene reacts with $HCl$ in the presence of peroxide,the product is

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