Which amino acid from the following is $NOT$ synthesized in our body?

The number of $sp^2$ hybridised carbons present in "Aspartame" is

Which of the following basic amino acids is the least basic?

Assertion: $\alpha$-amino acids exist as internal salt in solution as they have amino and carboxylic acid groups in near vicinity.
Reason: $H^{+}$ ion given by carboxylic group $(-COOH)$ is captured by amino group $(-NH_2)$ having lone pair of electrons.

Given below are two statements,one is labelled as Assertion $A$ and the other is labelled as Reason $R$.
Assertion $A$: $A$ solution of the product obtained by heating a mole of glycine with a mole of chlorine in the presence of red phosphorus generates a chiral carbon atom.
Reason $R$: $A$ molecule with $2$ chiral carbons is always optically active.
In the light of the above statements,choose the correct answer from the options given below:

Name the molecule which is eliminated during the formation of a peptide bond.