Which among the following halide$(s)$ will not show $S_{N}1$ reaction:
$(A)$ $H_2C=CH-CH_2Cl$
$(B)$ $CH_3-CH=CHCl$
$(C)$ $C_6H_5CH_2Cl$
$(D)$ $(CH_3)_2CHCl$
Choose the $most\ appropriate$ answer from the options given below:

  • A
    $(A)$,$(B)$ and $(D)$ only
  • B
    $(A)$ and $(B)$ only
  • C
    $(B)$ and $(C)$ only
  • D
    $(B)$ only

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Monochlorination of toluene in the presence of sunlight followed by hydrolysis gives:

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The following bimolecular elimination reaction $(E_2)$ is carried out with different halogen leaving groups. The per cent yield of the two products ($2$-hexene and $1$-hexene) for each leaving group is listed below.
Leaving groupConj. Acid $pK_a$$\%$-yield of $2$-hexene$\%$-yield of $1$-hexene
$X = I$$-10$$81\%$$19\%$
$X = Br$$-9$$72\%$$28\%$
$X = Cl$$-7$$67\%$$33\%$
$X = F$$3.2$$30\%$$70\%$

Which of the following statement$(s)$ is/are true concerning this series of $E_2$ reactions?

Compound $(A), \, C_8H_9Br,$ gives a white precipitate when warmed with alcoholic $AgNO_3.$ Oxidation of $(A)$ gives an acid $(B), \, C_8H_6O_4.$ $(B)$ easily forms anhydride on heating. Identify the compound $(A).$

The major product of the following reaction is:

Which one of the following compounds is most reactive towards $S_N1$ reaction?

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