Which compound is used to remove the temporary hardness of water in Clark's method?

Match the reactants in List-$I$ with the products in List-$II$.

List-$I$	List-$II$
$(a). H_2O + H_2S$	$(i). (H_3O^{+}, HS^{-})$
$(b). H_2O + N^{3-}$	$(ii). (NH_3, OH^{-})$
$(c). H_2O + SiCl_4$	$(iii). (OH^{-}, H_3S^{+})$
$(d). H_2O + F_2$	$(iv). (SiO_2, HCl)$
	$(v). (SiO_4^{4-}, Cl_2)$
	$(vi). (O_2, F^{-})$
	$(vii). (HF, OH^{-})$
	$(viii). (OH^{-}, NH_3)$

Heavy water $(D_2O)$ freezes at $.........$ $^oC$.

Write two reactions to explain the amphoteric nature of water.

Find the number of $CORRECT$ order against mentioned property :-
$(i)$ $D_2O = H_2O$ (number of electrons)
$(ii)$ $D_2O > H_2O$ $(|\Delta H_f|)$
$(iii)$ $D_2O > H_2O$ $(|\Delta H_{vaporization}|)$
$(iv)$ $D_2O > H_2O$ (density)
$(v)$ $D_2O > H_2O$ (Molecular mass)

Amongst the following,the form of water with the lowest ionic conductance at $298 \ K$ is