Which of the following has the strongest bond?

The reaction of $CH_3-CH=CH-C_6H_4-OH$ with $HBr$ gives:

$A$ body is projected from the ground at an angle of $\tan ^{-1}(\sqrt{7})$ with the horizontal. At half of the maximum height, the speed of the body is '$n$' times the speed of projection. The value of '$n$' is

The major products obtained from the reactions in List$-II$ are the reactants for the named reactions mentioned in List$-I.$ Match each entry in List$-I$ with the appropriate entry in List$-II$ and choose the correct options.

List$-I$	List$-II$
$(P)$ Stephen reaction	$(1)$ Toluene $\xrightarrow{\substack{\text { (i) } CrO _2 Cl _2 / CS _2 \\ \text { (ii) } H _3 O +}}$
$(Q)$ Sandmeyer reaction	$(2)$ Benzoic acid $\xrightarrow{\substack{\text { (i) } PCl _5 \\ \text { (iii) } NH _3 \\ \text { (iii) } P _4 O _{10}, \Delta}}$
$(R)$ Hoffmann bromamide degradation reaction	$(3)$ Nitrobenzene $\xrightarrow{\begin{array}{l}\text { (i) } Fe , HCl \\ \text { (ii) } HCl , NaNO _2 \\ \text { (273-278 K), } H _2 O \end{array}}$
$(S)$ Cannizzaro reaction	$(4)$ Toluene $\xrightarrow{\begin{array}{l}\text { (i) } Cl _2 / hv , H _2 O \\ \text { (ii) } \text {Tollen 's reagent } \\ \text { (iii) } SO _2 Cl _2 \\ \text { (iv) } NH _3\end{array}}$
	$(5)$ Aniline $\xrightarrow{\substack{\text { (i) }\left( CH _3 CO \right)_2 O , \text { Pyridine } \\ \text { (ii) } HN O _3 H _{2} SO _4, 288 K \\ \text { (iii) } aq . NaOH }}$

The angle between the lines represented by $\cos \theta(\cos \theta+1) x^2 - (2 \cos \theta + \sin^2 \theta) xy + (1 - \cos \theta) y^2 = 0$ is

Two liquids $A$ and $B$ have vapour pressures in the ratio $P_A^0 : P_B^0 = 1 : 3$ at a certain temperature. If the ratio of mole fractions of $A$ to $B$ in the vapour phase is $4 : 3$,then the mole fraction of $B$ in the solution at the same temperature is