Which of the following represents an incorrect electromeric effect?

  • A
    $>C=O \to >C^{+}-O^{-}$
  • B
    $CH_3-CH=CH_2 \to CH_3-CH^{+}-CH_2^{-}$
  • C
    $CH_3-C \equiv N \to CH_3-C^{-}=N^{+}$
  • D
    $CH \equiv CH \to CH^{+}=CH^{-}$

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What is the inductive effect? Explain it in detail.

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Explain the terms Inductive and Electromeric effects. Which electron displacement effect explains the following correct orders of acidity of the carboxylic acids?
$(a)$ $Cl_3CCOOH > Cl_2CHCOOH > ClCH_2COOH$
$(b)$ $CH_3CH_2COOH > (CH_3)_2CHCOOH > (CH_3)_3C \cdot COOH$

Represent the three types of electron movement in organic reactions.

In $CH_3(3) - CH_2(2) - CH_2(1) - Cl$,give the increasing order of the inductive effect for carbon atoms $1, 2,$ and $3$.

Identify the most stable species in the following set of ions giving reasons.
$(a) \ \stackrel{+}{C} H_{3}, \stackrel{+}{C} H_{2} Br, \stackrel{+}{C} HBr_{2}, \stackrel{+}{C} Br_{3}$
$(b) \ \stackrel{\Theta}{C} H_{3}, \stackrel{\Theta}{C} H_{2} Cl, \stackrel{\Theta}{C} HCl_{2}, \stackrel{\Theta}{C} Cl_{3}$

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