Which of the following amines will not react | vedclass

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(D) Primary amines $(R-NH_2)$ react with nitrous acid $(HNO_2)$ to form diazonium salts,which decompose to release $N_2$ gas.Secondary amines $(R_2NH)

Vedclass · Accepted Answer

$(CH_3)_3N$

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(D) Primary amines $(R-NH_2)$ react with nitrous acid $(HNO_2)$ to form diazonium salts,which decompose to release $N_2$ gas.Secondary amines $(R_2NH)$ react with $HNO_2$ to form $N$-nitrosoamines.Tertiary amines $(R_3N)$ do not contain an $\alpha-H$ atom on the nitrogen-bearing carbon (or rather,they lack the hydrogen necessary to form the intermediate required for $N_2$ evolution).Therefore,$(CH_3)_3N$ (a tertiary amine) does not react with nitrous acid to evolve $N_2$ gas.

Which of the following amines will not react with nitrous acid to give nitrogen gas?

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