Which of the following aqueous molal solutions has the highest freezing point?

What should be the freezing point of an aqueous solution containing $17 \ g$ of $C_2H_5OH$ in $1000 \ g$ of water? (Given: $K_f$ of water = $1.86 \ K \ kg \ mol^{-1}$)

Calculate the freezing point of a solution prepared by dissolving $1.8 \ g$ of glucose $(C_6H_{12}O_6)$ in $500 \ g$ of water. The $K_f$ value for water is $1.86 \ K \ kg \ mol^{-1}$. (in $K$)

$C_{6}H_{6}$ freezes at $5.5^{\circ} C$. The temperature at which a solution of $10 \ g$ of $C_{4}H_{10}$ in $200 \ g$ of $C_{6}H_{6}$ freezes is $...... \ ^{\circ} C$. (The molal freezing point depression constant of $C_{6}H_{6}$ is $5.12 \ ^{\circ} C/m$.)

$1.8 \ g$ of fructose is added to $2 \ kg$ of water. The freezing point of the solution is $(k_f = 1.86 \ K \ kg \ mol^{-1})$ (in $^\circ C$)

How much glucose $(molecular \ weight = 180 \ g/mol)$ should be added to $200 \ g \ H_2O$ so that when the solution is cooled to $-0.5^{\circ}C$,$14 \ g$ of ice separates out of the solution: [$K_f = 1.86 \ K \ kg/mol$ and melting point of $H_2O = 0^{\circ}C$] (in $g$)