Which of the following are used as catalysts in petroleum cracking?

$ \uparrow Y_{(g)} \xleftarrow{KI} CuSO_4 \xrightarrow{dil. H_2SO_4} X (\text{Blue colour}) $. $X$ and $Y$ are:

$X + KOH + O_2 \to Y + H_2O$,
$Y + H_2SO_4 \to Z + K_2SO_4 + MnO_2 + H_2O$
Identify $X, Y$ and $Z$ in the above reactions.

Which of the following oxides is amphoteric?

The yellow colour solution of $Na_2CrO_4$ changes to orange-red on passing $CO_2$ gas due to the formation of

Among $Co^{3+}$,$Ti^{2+}$,$V^{2+}$ and $Cr^{2+}$ ions,one if used as a reagent cannot liberate $H_{2}$ from dilute mineral acid solution,its spin-only magnetic moment in gaseous state is $.....$ $B.M.$ (Nearest integer)