Which of the following cannot be used as a standard solution for the determination of the cell constant of a conductivity cell?

  • A
    $1 \ M \ KCl$
  • B
    $0.1 \ M \ KCl$
  • C
    $0.01 \ M \ KCl$
  • D
    Saturated $KCl$

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Write a note on the difficulties associated with the measurement of resistivity of an ionic solution.

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Resistance of a cell containing $0.02 \ M \ KCl$ solution is $164 \ \Omega$. If the cell is filled with $0.05 \ M \ AgNO_3$,the resistance becomes $75.8 \ \Omega$. Calculate the following: [Conductivity of $0.02 \ M \ KCl = 2.768 \times 10^{-3} \ \Omega^{-1} \ cm^{-1}$] $(i)$ Conductivity of $0.05 \ M \ AgNO_3$ (ii) Molar conductivity of $AgNO_3$ solution.

The conductivity of sodium chloride at $298 \ K$ has been determined at different concentrations and the results are given below:
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Calculate ${\Lambda _m}$ for all concentrations and draw a plot between ${\Lambda _m}$ and $c^{1/2}$. Find the value of $\Lambda _m^o$.

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