Which of the following combinations does not evolve $Cl_2$ gas?

The reaction of $Na_2S_2O_3$ with iodine gives

Assign $A, B, C, D$ from the given type of reaction.
$KMnO_4 + NaNO_3 \longrightarrow$ No reaction

$20 \ mL$ of $Fe^{2+}$ solution of certain concentration has completely reacted with $20 \ mL$ of $0.01 \ M \ K_2Cr_2O_7$ in acidic medium. If $20 \ mL$ of same $Fe^{2+}$ solution has reacted completely with $20 \ mL$ of $KMnO_4$ solution in acidic medium,the molarity of $KMnO_4$ solution is: (in $M$)

Given below are two statements:
Statement-$I$ : Heating $NaCl$ with concentrated $H_2SO_4$ and $MnO_2$ results in oxidation of $Mn$.
Statement-$II$ : Heating $NaI$ with concentrated $H_2SO_4$ and $MnO_2$ results in reduction of $Mn$.
In light of the above statements, choose the most appropriate answer from the options given below:

Which of the following reactions does not involve either oxidation or reduction?