Which of the following complex ions does not exist?

Draw the structure of $Al_2Cl_6$ and give the uses of $AlCl_3$.

In the following sets of reactants,which two sets best exhibit the amphoteric character of $Al_2O_3 \cdot xH_2O$?
Set $1$: $Al_2O_3 \cdot xH_2O_{(s)}$ and $OH^{-}_{(aq)}$
Set $2$: $Al_2O_3 \cdot xH_2O_{(s)}$ and $H_2O_{(l)}$
Set $3$: $Al_2O_3 \cdot xH_2O_{(s)}$ and $H^{+}_{(aq)}$
Set $4$: $Al_2O_3 \cdot xH_2O_{(s)}$ and $NH_{3(aq)}$

$Al_2O_3$ reacts with

The correct statements among $I$ to $III$ regarding group $13$ element oxides are,
$I$. Boron trioxide is acidic
$II$. Oxides of aluminium and gallium are amphoteric
$III$. Oxides of indium and thallium are basic

Statement-$1$: Orthoboric acid acts as a weak monobasic acid in water.
Statement-$2$: Orthoboric acid acts as a proton donor in water.