Which of the following complexes does the central metal ion $NOT$ obey the $EAN$ rule? (Atomic numbers: $Pt=78, Cu=29, Zn=30, Fe=26$)

The Effective Atomic Number $(EAN)$ rule is less likely to be followed if the metal-ligand bond is of which type?

$a$. Answer the following questions:
$i$. Which element of the first transition series has the highest second ionisation enthalpy?
$ii$. Which element of the first transition series has the highest third ionisation enthalpy?
$iii$. Which element of the first transition series has the lowest enthalpy of atomisation?
$b$. Identify the metal and justify your answer:
$i$. Carbonyl $M(CO)_5$
$ii$. $MO_3F$

Which one of the following does not follow Sidgwick $EAN$ rule?

The $EAN$ of iron in potassium ferricyanide is

Among $V(CO)_6$,$Cr(CO)_5$,$Cu(CO)_3$,$Mn(CO)_5$,$Fe(CO)_5$,$[Co(CO)_3]^{3-}$,$[Cr(CO)_4]^{4-}$,and $Ir(CO)_3$,the total number of species isoelectronic with $Ni(CO)_4$ is. . . . . [Given atomic number : $V=23$,$Cr=24$,$Mn=25$,$Fe=26$,$Co=27$,$Ni=28$,$Cu=29$,$Ir=77$ ]