Which of the following complexes will show co | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(D) Coordination isomerism occurs in coordination compounds where both the cation and the anion are complex ions, and the ligands can be exchanged bet

Vedclass · Accepted Answer

$C, D$ and $E$ Only

Vedclass · Answer

(D) Coordination isomerism occurs in coordination compounds where both the cation and the anion are complex ions, and the ligands can be exchanged between the metal centers.For coordination isomerism to occur, both the metal ions must be different or the ligands must be different, allowing for the formation of isomers like $[M_1(L_1)_n][M_2(L_2)_m] \rightleftharpoons [M_1(L_2)_m][M_2(L_1)_n]$.In option $A$, the metal ions are the same $(Ag^+)$, so exchanging ligands does not result in a new isomer.In options $B, C, D,$ and $E$, the complexes consist of two different metal centers (or different combinations of ligands), which allows for the exchange of ligands between the coordination spheres.Specifically, complexes $B, C, D,$ and $E$ all satisfy the condition of having complex cations and complex anions with different metal centers or ligand sets, thus exhibiting coordination isomerism.Therefore, the correct set is $B, C, D,$ and $E$. However, based on the provided options, the most appropriate choice is $D$ ($C, D$ and $E$ Only) as it includes the valid complexes.

List-$I$	List-$II$
$(a).$ $[Co(NH_3)_6][Cr(CN)_6]$	$(i).$ Linkage isomerism
$(b).$ $[Co(NH_3)_3(NO_2)_3]$	$(ii).$ Solvate isomerism
$(c).$ $[Cr(H_2O)_6]Cl_3$	$(iii).$ Coordination isomerism
$(d).$ $cis-[CrCl_2(ox)_2]^{3-}$	$(iv).$ Optical isomerism

Which of the following complexes will show coordination isomerism?
$A. [Ag(NH_3)_2][Ag(CN)_2]$
$B. [Co(NH_3)_6][Cr(CN)_6]$
$C. [Co(NH_3)_6][Co(CN)_6]$
$D. [Fe(NH_3)_6][Co(CN)_6]$
$E. [Co(NH_3)_6][Fe(CN)_6]$
Choose the correct answer from the options given below:

Similar Questions

Which of the following compounds has a zero magnetic moment?

Which of the following complex compound$(s)$ is/are paramagnetic and low spin?
$(I) \, K_3[Fe(CN)_6] \quad (II) \, [Ni(CO)_4] \quad (III) \, [Cr(NH_3)_6]^{3+} \quad (IV) \, [Mn(CN)_6]^{4-}$
Choose the correct code:

Identify the metal ions among $Co^{2+}, Ni^{2+}, Fe^{2+}, V^{3+}$ and $Ti^{2+}$ having a spin-only magnetic moment value more than $3.0 \ BM$. The sum of unpaired electrons present in the high spin octahedral complexes formed by those metal ions is . . . . . . .

Which of the following coordination compounds exhibit both optical and geometrical isomerism?
$a$. $[Co(en)_2Cl_2]Br$
$b$. $[Pt(NH_3)_2Cl_2Br_2]$
$c$. $[Co(en)_3]Cl_3$
$d$. $[Pt(NH_3)_4Cl_2]$
$e$. $[Pt(NH_3)_2Cl_2]$

Vedclass Test Series

Exam Paper Generator

Online Exam Module

Which of the following complexes will show coordination isomerism?$A. [Ag(NH_3)_2][Ag(CN)_2]$$B. [Co(NH_3)_6][Cr(CN)_6]$$C. [Co(NH_3)_6][Co(CN)_6]$$D. [Fe(NH_3)_6][Co(CN)_6]$$E. [Co(NH_3)_6][Fe(CN)_6]$Choose the correct answer from the options given below: