Which of the following compounds is brown coloured?

Select the correct statement$(s)$ regarding the $[Ni(DMG)_2]$ complex compound.

The number of ions present in $2.0 \ L$ of a solution of $0.8 \ M \ K_4[Fe(CN)_6]$ is

The reaction of $K_3[Fe(CN)_6]$ with freshly prepared $FeSO_4$ solution produces a dark blue precipitate called Turnbull's blue. The reaction of $K_4[Fe(CN)_6]$ with $FeSO_4$ solution in the complete absence of air produces a white precipitate $X$,which turns blue in air. Mixing the $FeSO_4$ solution with $NaNO_3$,followed by a slow addition of concentrated $H_2SO_4$ through the side of the test tube,produces a brown ring.
Precipitate $X$ is:
$(A)$ $Fe_4[Fe(CN)_6]_3$
$(B)$ $Fe[Fe(CN)_6]$
$(C)$ $K_2Fe[Fe(CN)_6]$
$(D)$ $KFe[Fe(CN)_6]$
Among the following,the brown ring is due to the formation of:
$(A)$ $[Fe(NO)_2(SO_4)_2]^{2-}$
$(B)$ $[Fe(NO)_2(H_2O)_4]^{3+}$
$(C)$ $[Fe(NO)_4(SO_4)_2]$
$(D)$ $[Fe(H_2O)_5(NO)]SO_4$

The correct option(s) about entropy $(S)$ is(are)
$[R =$ gas constant, $F =$ Faraday constant, $T =$ Temperature $]$
$(A)$ For the reaction, $M_{(s)} + 2H^{+}_{(aq)} \rightarrow H_{2(g)} + M^{2+}_{(aq)}$, if $\frac{dE_{cell}}{dT} = \frac{R}{F}$, then the entropy change of the reaction is $R$ (assume that entropy and internal energy changes in entropy and internal energy are temperature independent).
$(B)$ The cell reaction, $Pt_{(s)} \mid H_2(g, 1 \ bar) \mid H^{+}(aq, 0.01 \ M) \parallel H^{+}(aq, 0.1 \ M) \mid H_2(g, 1 \ bar) \mid Pt_{(s)}$, is an entropy driven process.
$(C)$ For racemization of an optically active compound, $\Delta S > 0$.
$(D)$ $\Delta S > 0$, for $[Ni(H_2O)_6]^{2+} + 3en \rightarrow [Ni(en)_3]^{2+} + 6H_2O$ (where $en =$ ethylenediamine).

When potassium iodide is added to an aqueous solution of potassium ferricyanide,a reversible reaction is observed in which a complex $P$ is formed. In a strong acidic medium,the equilibrium shifts completely towards $P$. Addition of zinc chloride to $P$ in a slightly acidic medium results in a sparingly soluble complex $Q$.
$(1)$ The number of moles of potassium iodide required to produce two moles of $P$ is. . .
$(2)$ The number of zinc ions present in the molecular formula of $Q$ is. . . .
Give the answer for $(1)$ and $(2)$.