Which of the following contains both ionic and covalent bonds?

$A$ uniform rope of length $L$ and mass $m_1$ hangs vertically from a rigid support. $A$ block of mass $m_2$ is attached to the free end of the rope. $A$ transverse pulse of wavelength $\lambda_1$ is produced at the lower end of the rope. The wavelength of the pulse when it reaches the top of the rope is $\lambda_2$. The ratio $\lambda_2/\lambda_1$ is

In a quadrilateral $ABCD$,the point $P$ divides $DC$ in the ratio $1:2$ and $Q$ is the midpoint of $AC$. If $\overrightarrow{AB}+2\overrightarrow{AD}+\overrightarrow{BC}-2\overrightarrow{DC}=k\overrightarrow{PQ}$,then $k$ is equal to

Which of the following is not an antibiotic?

Which of the following orbitals has zero probability of finding the electron in the $YZ$ plane?

Which of the following is a herbicide?