Which of the following endothermic processes are spontaneous?

When $200 \ cm^3$ of $0.1 \ M \ H_2SO_4$ is mixed with $150 \ cm^3$ of $0.2 \ M \ KOH$,the heat produced is ..... $kJ$.

An ideal gas undergoes a reversible cyclic process as shown in the figure. The work done in this process is: (in $,V_1P_1$)

For the reaction,$2Cl_{(g)} \to Cl_{2(g)}$,the signs of $\Delta H$ and $\Delta S$ respectively,are:

What is the enthalpy of vaporization of ethanol in $kJ/mol$? Given: boiling point $(b.p.)$ = $79.5 \, ^\circ C$ and entropy change $(\Delta S_{vap})$ = $109.8 \, J K^{-1} mol^{-1}$.

$A$ gas (Molar mass $= 280 \ g \ mol^{-1}$) was burnt in excess $O_2$ in a constant volume calorimeter and during combustion the temperature of calorimeter increased from $298.0 \ K$ to $298.45 \ K$. If the heat capacity of calorimeter is $2.5 \ kJ \ K^{-1}$ and enthalpy of combustion of gas is $9 \ kJ \ mol^{-1}$,then the amount of gas burnt is $...... \ g$. (Nearest Integer)