Which of the following is the correct expression for an irreversible process?

Standard entropy of $X_2, Y_2$ and $XY_3$ are $60, 40$ and $50 \ J \ K^{-1} \ mol^{-1},$ respectively. For the reaction,$\frac{1}{2}X_2 + \frac{3}{2}Y_2 \to XY_3, \ \Delta H = -30 \ kJ,$ to be at equilibrium,the temperature will be ............... $K$.

Which state functions are required to understand the second law of thermodynamics?

If the enthalpy change for the transition of liquid water to steam is $30 \ kJ \ mol^{-1}$ at $27 \ ^oC,$ the entropy change for the process would be ............. $J \ mol^{-1} \ K^{-1}$

Will ice at $273 \ K$ placed in a surrounding at $298 \ K$ melt to form water at $273 \ K$? Prove this statement. The molar enthalpy of fusion of ice is $6.025 \ kJ \ mol^{-1}$.

Direct conversion of $A$ to $B$ is difficult,so it is carried out by the path shown below. If $e.u.$ is the entropy unit,what will be $\Delta S_{(A \rightarrow B)}$?
Given:
$\Delta S_{(A \rightarrow C)} = 50 \ e.u.$
$\Delta S_{(C \rightarrow D)} = 30 \ e.u.$
$\Delta S_{(B \rightarrow D)} = 20 \ e.u.$