Which of the following is a correct reaction?

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(D) All the given reactions are standard controlled oxidation reactions of alkanes:$1$. Controlled oxidation of methane with $Cu$ at $523 \ K$ and $10

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(D) All the given reactions are standard controlled oxidation reactions of alkanes:$1$. Controlled oxidation of methane with $Cu$ at $523 \ K$ and $100 \ atm$ yields methanol: $2 CH_4 + O_2 \xrightarrow{Cu / 523 \ K / 100 \ atm} 2 CH_3OH$.$2$. Controlled oxidation of methane with $Mo_2O_3$ yields methanal: $CH_4 + O_2 \xrightarrow{Mo_2O_3} HCHO + H_2O$.$3$. Oxidation of alkanes having a tertiary hydrogen atom with $KMnO_4$ yields the corresponding tertiary alcohol: $(CH_3)_3CH \xrightarrow{KMnO_4} (CH_3)_3COH$.

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