Which of the following is not the correct order of inductive effect?

  • A
    $CH_3-C(CH_3)_2- > (CH_3)_2CH-CH_2- > -CH_2-CH_2-CH_2-CH_3$ ($+I$ effect)
  • B
    $-NO_2 > -CN > -F$ ($-I$ effect)
  • C
    $-NH_2 > -C \equiv CH > -CH = CH_2$ ($-I$ effect)
  • D
    $-CH_2^- > -O^- > -COO^-$ ($+I$ effect)

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Which of the following $\sigma$-bonds participate in hyperconjugation?

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Which of the following statements are not correct?
$a$. The energy of resonance hybrid structure is higher than that of the possible canonical structures of the molecule.
$b$. When inductive effect and electromeric effect operate in opposite directions,electromeric effect predominates.
$c$. When the $\pi$ electrons of the multiple bond are transferred to that atom to which the attacking reagent does not get attached,it is known as $+E$ effect.
$d$. The resonance structures with separation of opposite charges are more stable.

Given below are two statements:
Statement $I:$ Hyperconjugation is a permanent effect.
Statement $II:$ Hyperconjugation in ethyl cation $(CH_{3}CH_{2}^{+})$ involves the overlapping of $C_{sp^{3}}-H_{1s}$ bond with the empty $2p$ orbital of the adjacent carbon.
Choose the correct option:

The following effect is known as . . . . . .

Identify ortho and para directing groups from the following: $I. -CHO$,$II. -NHCOCH_3$,$III. -OCH_3$,$IV. -SO_3H$.

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