Which of the following is a spin-free complex?

  • A
    $[Fe(H_2O)_6]Cl_2$
  • B
    $K_4[Fe(CN)_6]$
  • C
    $[Ni(CO)_4]$
  • D
    $[Ni(CN)_4]^{2-}$

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The molecular formula of a cobalt coordination complex contains five ammonia molecules,one nitro group,and two chlorine atoms for one cobalt atom. In an aqueous solution,one mole of the substance produces $3$ moles of ions. Upon reacting this solution with an excess of silver nitrate solution,$2$ moles of $AgCl$ precipitate are obtained. What is the ionic formula of the complex?

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In ${K_4}[Fe(CN)_6]$,$Fe$ is in the form of

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Which one is the most likely structure of $CrCl_3 \cdot 6H_2O$ if $1/3$ of total chlorine of the compound is precipitated by adding $AgNO_3$ to its aqueous solution?

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The stepwise stability constants of a complex are given below. What is its overall reaction stability constant $\beta_4$ ?
$M + L \rightleftharpoons ML ; K_1 = 1.0 \times 10^4$
$ML + L \rightleftharpoons ML_2 ; K_2 = 1.0 \times 10^3$
$ML_2 + L \rightleftharpoons ML_3 ; K_3 = 1.0 \times 10^3$
$ML_3 + L \rightleftharpoons ML_4 ; K_4 = 1.0 \times 10^2$
(Overall reaction : $M + 4L \rightleftharpoons ML_4$)

Which of the following complex ions has the least stability?

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