Which of the following is the correct increasing order of ligand field strength according to the spectrochemical series?
- A$EDTA^{4-} < C_2O_4^{2-} < H_2O < en$
- B$en < H_2O < EDTA^{4-} < C_2O_4^{2-}$
- C$C_2O_4^{2-} < H_2O < EDTA^{4-} < en$
- D$H_2O < C_2O_4^{2-} < EDTA^{4-} < en$
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The stepwise stability constants of a complex are given below. What is its overall reaction stability constant $\beta_4$ ?
$M + L \rightleftharpoons ML ; K_1 = 1.0 \times 10^4$
$ML + L \rightleftharpoons ML_2 ; K_2 = 1.0 \times 10^3$
$ML_2 + L \rightleftharpoons ML_3 ; K_3 = 1.0 \times 10^3$
$ML_3 + L \rightleftharpoons ML_4 ; K_4 = 1.0 \times 10^2$
(Overall reaction : $M + 4L \rightleftharpoons ML_4$)
$M + L \rightleftharpoons ML ; K_1 = 1.0 \times 10^4$
$ML + L \rightleftharpoons ML_2 ; K_2 = 1.0 \times 10^3$
$ML_2 + L \rightleftharpoons ML_3 ; K_3 = 1.0 \times 10^3$
$ML_3 + L \rightleftharpoons ML_4 ; K_4 = 1.0 \times 10^2$
(Overall reaction : $M + 4L \rightleftharpoons ML_4$)
Which of the following is a strong field ligand?
Aluminium trifluoride is insoluble in anhydrous $HF$ but dissolves on addition of $NaF$. Aluminium trifluoride precipitates out of the resulting solution when gaseous $BF_3$ is bubbled through. Give reasons.
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View SolutionWhich of the following has the maximum molar conductivity?
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