Which of the following is the strongest base?

Compound $III$ is
$\xrightarrow[{ii)\,CuCl/HCl}]{{i)\,HNO_2\,(0 - 5\,^oC)}}I$ $\xrightarrow{{Sn/HCl}}II$ $\xrightarrow[{ii)\,H_3PO_2 + H_2O}]{{i)HNO_2\,(0 - 5\,^oC)\,}}III$

Which of the following compounds does not give alcohol on reduction?

Which of the following will not give Hoffmann bromamide reaction?

Given below are two statements :
Statement $I$: Aniline reacts with conc. $H_2SO_4$ followed by heating at $453-473 \ K$ to give $p$-aminobenzene sulphonic acid (sulphanilic acid). This compound contains both nitrogen and sulphur,and thus it gives a blood red colour in the 'Lassaigne's test' due to the formation of ferric thiocyanate,$[Fe(SCN)]^{2+}$.
Statement $II$: In Friedel-Craft's alkylation and acylation reactions,aniline forms a salt with the $AlCl_3$ catalyst. Due to this,the nitrogen atom of aniline acquires a positive charge and acts as a deactivating group,preventing further reaction.
In the light of the above statements,choose the correct answer from the options given below :

Identify $Z$ in the above sequence of reactions.