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Which of the following sets of quantum numbers is not possible for an electron?

In an element with atomic number $(Z) = 25$,the number of electrons with $(n+l)$ value equal to $3$ and $4$ are $x$ and $y$ respectively. The value of $(x+y)$ is

The $d$ orbital with the orientation along $X$ and $Y$ axis is called.

In an atom,the total number of electrons having quantum numbers $n=4$,$|m_{\ell}|=1$ and $m_s=-1/2$ is

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