Which of the following pairs of solutions is expected to be isotonic at the same temperature?

Isotonic solutions have the same

$A$ solution of $8 \ g$ of a certain organic compound in $2 \ dm^3$ of water develops an osmotic pressure of $0.6 \ atm$ at $300 \ K$. Calculate the molar mass of the compound. $\left[R = 0.082 \ atm \ dm^3 \ K^{-1} \ mol^{-1}\right]$

The osmotic pressure of sea water is $1.05 \ atm$. Four experiments were carried out as shown in the table below. In which of the following experiments can pure water be obtained in part-$II$ of the vessel?
| Experiment | Pressure applied on part-$I$ $(atm)$ | Pressure applied on part-$II$ $(atm)$ |
| :--- | :--- | :--- |
| $I$ | $2.0$ | $1.0$ |
| $II$ | $1.0$ | $2.0$ |
| $III$ | $3.0$ | $1.0$ |
| $IV$ | $1.0$ | $1.0$ |

$A$ $25 \%$ solution of cane-sugar (molar mass $= 342 \ g \ mol^{-1}$) is isotonic with a $5 \%$ solution of a substance $A$. Find the molecular weight of $A$.

At $27^{\circ}C$, $0.1 \ M$, $1 \ L$ $K_4[Fe(CN)_6]$ aqueous solution and $0.1 \ M$, $1 \ L$ $FeCl_3$ aqueous solution are placed in a container separated by a semi-permeable membrane $AB$. Assume complete dissociation of both the solutes. Which of the following statements is correct?