Which of the following processes takes place with a decrease of entropy?

When $2 \ mol$ of an ideal gas $\left( C_{p,m} = \frac{5}{2} R \right)$ is heated from $300 \ K$ to $600 \ K$ at constant pressure,the change in entropy of the gas $\left( \Delta S \right)$ is:

What is the unit of $\Delta S_m^\circ$?

One mole of an ideal gas at $350 \, K$ is in a $2.0 \, L$ vessel with thermally conducting walls,which are in contact with the surroundings. It undergoes isothermal expansion from $2.0 \, L$ to $3.0 \, L$ against a constant external pressure of $4 \, atm$. The change in entropy of the surroundings $(\Delta S_{surr})$ is $...... \, J \, K^{-1}$ (Nearest integer). Given: $R = 8.314 \, J \, K^{-1} \, mol^{-1}$.

For the following process $H_2O_{(l)} (1 \ bar, 373.15 \ K) \rightleftharpoons H_2O_{(g)} (1 \ bar, 373.15 \ K)$, identify the correct set of thermodynamic parameters.

One mole of water at $100\,^{\circ}C$ is converted into steam at $100\,^{\circ}C$ at a constant pressure of $1\,atm$. The change in entropy is [heat of vaporisation of water at $100\,^{\circ}C = 540\,cal/g$].