Which of the following reactants will not favour nucleophilic substitution reaction?

Match the reactions in List-$I$ with the features of their products in List-$II$ and choose the correct option.
| List-$I$ | List-$II$ |
| :--- | :--- |
| $(P)$ $(-)-1$-Bromo-$2$-ethylpentane $\xrightarrow{aq. NaOH, S_N2}$ | $(1)$ Inversion of configuration |
| $(Q)$ $(-)-2$-Bromopentane $\xrightarrow{aq. NaOH, S_N2}$ | $(2)$ Retention of configuration |
| $(R)$ $(-)-3$-Bromo-$3$-methylhexane $\xrightarrow{aq. NaOH, S_N1}$ | $(3)$ Mixture of enantiomers |
| $(S)$ $(3S, 5S)-5$-bromo-$3$-methylheptane $\xrightarrow{aq. NaOH, S_N1}$ | $(4)$ Mixture of structural isomers |
| | $(5)$ Mixture of diastereomers |

$(i) \, (CH_3)_2CH-CH_2Br \xrightarrow{C_2H_5OH} (CH_3)_2CH-CH_2OC_2H_5 + HBr$
$(ii) \, (CH_3)_2CH-CH_2Br \xrightarrow{C_2H_5O^-} (CH_3)_2CH-CH_2OC_2H_5 + Br^-$
The reaction mechanisms for $(i)$ and $(ii)$ are respectively:

In nucleophilic aliphatic substitution,the nucleophiles are generally

Which of the following undergoes nucleophilic substitution by $S_N1$ mechanism?

Identify the Finkelstein reaction from the following.