Which of the following reactions is incorrect?

  • A
    $Ag_2O + H_2O_2 \to 2Ag + H_2O + O_2$
  • B
    $PbS + 4H_2O_2 \to PbSO_4 + 4H_2O$
  • C
    $Fe^{2+} + H_2O_2 \xrightarrow{\text{basic}} Fe^{3+} + 2OH^-$
  • D
    $Mn^{2+} + H_2O_2 \xrightarrow{\text{basic}} Mn^{4+} + 2OH^-$

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Assertion $:$ Amount of $H_2O_2$ in a sample can be determined by treating $H_2O_2$ solution with $KI$ and followed by titration of liberated $I_2$ with sodium thiosulphate.
Reason $:$ In this titration,an intense blue colour appears which disappears at the end point.

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What is the approximate volume (in $mL$) of $10$ vol $H_2O_2$ solution that will react completely with $1 \ L$ of $0.02 \ M \ KMnO_4$ solution in acidic medium?

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