Which of the following reactions is not an example of electrophilic substitution?

Toluene has

Match the following reactions given in Column-$I$ with their respective names in Column-$II$:

Column-$I$	Column-$II$
$(i)$ $\text{Benzene} + \text{Conc. } HNO_3 + \text{Conc. } H_2SO_4 \rightarrow \text{Nitrobenzene}$	$(A)$ $\text{Halogenation}$
$(ii)$ $\text{Benzene} + Cl_2 \xrightarrow{\text{Anhy. } AlCl_3} \text{Chlorobenzene}$	$(B)$ $\text{Nitration}$
$(iii)$ $\text{Benzene} + CH_3Cl \xrightarrow{\text{Anhy. } AlCl_3} \text{Toluene}$	$(C)$ $\text{Friedel-Crafts acylation}$
$(iv)$ $\text{Benzene} + CH_3COCl \xrightarrow{\text{Anhy. } AlCl_3} \text{Acetophenone}$	$(D)$ $\text{Friedel-Crafts alkylation}$

What is obtained by the bromination of benzene in the presence of $U.V.$ light?

How will you convert benzene into:
$I$. $p$-nitrotoluene
$II$. acetophenone

Given below are two statements. One is labelled as Assertion $A$ and the other is labelled as Reason $R$.
Assertion $A$: $[6]-$Annulene,$[8]-$Annulene and cis$-10-$Annulene are respectively aromatic,non-aromatic and non-aromatic.
Reason $R$: Planarity is one of the requirements of aromatic systems.
In the light of the above statements,choose the most appropriate answer from the options given below.