Which of the following reactions is not exothermic?

$C_{(s)} + O_{2(g)} \rightarrow CO_{2(g)} \dots \dots(I) \quad \Delta H = -393 \, kJ \, mol^{-1}$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \rightarrow H_{2}O_{(l)} \dots \dots(II) \quad \Delta H = -287.3 \, kJ \, mol^{-1}$
$2CO_{2(g)} + 3H_{2}O_{(l)}$ $\rightarrow C_{2}H_{5}OH_{(l)} + 3O_{2(g)} \dots \dots(III) \quad \Delta H = 1366.8 \, kJ \, mol^{-1}$
Find the standard enthalpy of formation of $C_{2}H_{5}OH_{(l)}$.

Hess's law of constant heat summation is based on

If the enthalpy of combustion of carbon to $CO_{2(g)}$ is $-394.0 \ kJ \ mol^{-1}$,the enthalpy change for the formation of $17.6 \ g$ of $CO_2$ from carbon and dioxygen at the same temperature in $kJ$ is:

Average $C-H$ bond energy is $416 \ kJ \ mol^{-1}$. Which of the following is correct?

Consider the following reactions:
$(i)$ $H_{(aq)}^{+} + OH^{-}_{(aq)} \longrightarrow H_2O_{(l)}$,$\Delta H = -X_1 \ kJ \ mol^{-1}$
$(ii)$ $H_{2_{(g)}} + \frac{1}{2} O_{2_{(g)}} \longrightarrow H_2O_{(l)}$,$\Delta H = -X_2 \ kJ \ mol^{-1}$
$(iii)$ $CO_{2_{(g)}} + H_{2_{(g)}} \longrightarrow CO_{(g)} + H_2O_{(l)}$,$\Delta H = -X_3 \ kJ \ mol^{-1}$
$(iv)$ $C_2H_{2_{(g)}} + \frac{5}{2} O_{2_{(g)}} \longrightarrow 2CO_{2_{(g)}} + H_2O_{(l)}$,$\Delta H = -X_4 \ kJ \ mol^{-1}$
Enthalpy of formation of $H_2O_{(l)}$ is