Which of the following reactions will not give a primary amine?

  • A
    $CH_3CONH_2 \xrightarrow{KOH, Br_2}$
  • B
    $CH_3CN \xrightarrow{LiAlH_4}$
  • C
    $CH_3NC \xrightarrow{LiAlH_4}$
  • D
    $CH_3CONH_2 \xrightarrow{LiAlH_4}$

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Which of the following species would not be involved in the Hoffmann rearrangement shown below?

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$X \ g$ of ethanamine was subjected to reaction with $NaNO_2 / HCl$ followed by hydrolysis to liberate $N_2$ and $HCl$. The $HCl$ generated was completely neutralized by $0.2 \ mol$ of $NaOH$. $X$ is . . . .

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