Which of the following solutions does not act as a buffer $:-$

What is the $pH$ of $10 \ L$ of a buffer solution containing $0.01 \ M \ NH_4Cl$ and $0.1 \ M \ NH_4OH$ having $pK_b$ of $5$?

The $pK_a$ of a weak acid $(HA)$ is $4.5$. The $pOH$ of an aqueous buffered solution of $HA$ in which $50\%$ of the acid is neutralized in its titration with a strong base $(BOH)$ is

One litre of an aqueous solution contains $0.15 \ mol$ of $CH_3COOH$ $(pK_a = 4.8)$ and $0.15 \ mol$ of $CH_3COONa$. After the addition of $0.05 \ mol$ of solid $NaOH$ to this solution,the $pH$ will be:

An acidic buffer is obtained on mixing

Assertion : In a titration of weak acid and $NaOH$,the $pH$ at half equivalence point is $pK_a$.
Reason : At half equivalence point,it forms an acidic buffer and the buffer capacity is maximum where $[acid] = [salt]$.