Which of the following statement is/are $TRUE$?

  • A
    In metal carbonyls, $d_{C-O}$ is more as compared to that in $CO$ molecule
  • B
    The pair of compounds $[Cr(H_2O)_6]Cl_3$ and $[CrCl_3(H_2O)_3] \cdot 3H_2O$ show hydrate isomerism
  • C
    $d_{z^2}$ orbital of central metal atom/ion is used in $dsp^2$ hybridisation
  • D
    Facial and meridional isomers are associated with $[Ma_3b_3]^{n\pm}$ type complex and are optically active

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Match List-$I$ with List-$II$ and select the correct option:
List-$I$List-$II$
$(A). [Ag(CN)_2]^-$$1. \text{Square planar, } 1.73 \, B.M.$
$(B). [Cu(CN)_4]^{3-}$$2. \text{Linear, } 0 \, B.M.$
$(C). [Cu(CN)_6]^{4-}$$3. \text{Octahedral, } 0 \, B.M.$
$(D). [Cu(NH_3)_4]^{2+}$$4. \text{Tetrahedral, } 0 \, B.M.$
$(E). [Fe(CN)_6]^{4-}$$5. \text{Octahedral, } 1.73 \, B.M.$

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In basic medium, the amount of $Ni^{2+}$ in a solution can be estimated with the dimethylglyoxime reagent. The correct statement$(s)$ about the reaction and the product is (are):

Among the statements $(a)-(d)$,the incorrect ones are:
$(a)$ Octahedral $Co(III)$ complexes with strong field ligands have very high magnetic moments.
$(b)$ When $\Delta_{0} < P$,the $d-$electron configuration of $Co(III)$ in an octahedral complex is $t_{2g}^{4} e_{g}^{2}$.
$(c)$ Wavelength of light absorbed by $[Co(en)_{3}]^{3+}$ is lower than that of $[CoF_{6}]^{3-}$.
$(d)$ If the $\Delta_{0}$ for an octahedral complex of $Co(III)$ is $18,000 \ cm^{-1}$,the $\Delta_{t}$ for its tetrahedral complex with the same ligand will be $16,000 \ cm^{-1}$.

Choose the correct statement$(s)$ among the following:
$(A)$ $[FeCl_4]^-$ has tetrahedral geometry.
$(B)$ $[Co(en)(NH_3)_2Cl_2]^+$ has $2$ geometrical isomers.
$(C)$ $[FeCl_4]^-$ has higher spin-only magnetic moment than $[Co(en)(NH_3)_2Cl_2]^+$.
$(D)$ The cobalt ion in $[Co(en)(NH_3)_2Cl_2]^+$ has $sp^3d^2$ hybridization.

Which statement is wrong?

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