Which of the following statements is correct for any thermodynamic system?

$A$ hot piece of copper at $100^{\circ} C$ is dropped into a pond at $30^{\circ} C$. The copper cools down to $30^{\circ} C$,while the pond remains at its initial temperature due to its large size. Then,

$N_{2}$ gas is heated from $300\, K$ to $600\, K$ through an isobaric process. Find the change in entropy of the gas. $(n = 1\, \text{mole})$ (in $J/K$)

Write an example in which the first law of thermodynamics is allowed but is never observed.

$A$ solid body of constant heat capacity $1\,J/^{\circ}C$ is being heated by keeping it in contact with reservoirs in two ways:
$(i)$ Sequentially keeping in contact with $2$ reservoirs such that each reservoir supplies the same amount of heat.
$(ii)$ Sequentially keeping in contact with $8$ reservoirs such that each reservoir supplies the same amount of heat.
In both cases, the body is brought from an initial temperature $100^{\circ}C$ to a final temperature $200^{\circ}C$. The entropy change of the body in the two cases respectively is:

The fundamental limitation to the coefficient of performance of a refrigerator is given by