Which of the following statements is true about the equilibrium constant and rate constant of a single-step chemical reaction?

  • A
    Equilibrium constant may increase or decrease but rate constant always increases with temperature
  • B
    Both equilibrium constant and rate constant increase with temperature
  • C
    Rate constant may increase or decrease but equilibrium constant always increases with temperature
  • D
    Both equilibrium constant and rate constant decrease with temperature

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The rate constant of a reaction varies with temperature according to the equation: $\log K = \text{constant} - \frac{E_a}{2.303 RT}$. If a plot of $\log K$ versus $1/T$ yields a straight line with a slope of $-5632$,then the activation energy of the reaction is .......... $kJ \ mol^{-1}$.

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For the forward reaction $X \rightarrow Y$,the activation energy is $60 \ kJ \ mol^{-1}$ and $\Delta H = -20 \ kJ \ mol^{-1}$. What is the activation energy for the reverse reaction $Y \rightarrow X$ in $kJ \ mol^{-1}$?

$A$ reaction having equal activation energies for forward and reverse reaction has:

The following energy profile diagram is given for the reaction $A + B \to C + D$. The enthalpy change and activation energy for the reverse reaction $C + D \to A + B$ are respectively:

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The energies of activation for forward and reverse reactions for $A_2 + B_2 \rightleftharpoons 2AB$ are $180 \, kJ \, mol^{-1}$ and $200 \, kJ \, mol^{-1}$ respectively. The presence of a catalyst lowers the activation energy of both (forward and reverse) reactions by $100 \, kJ \, mol^{-1}.$ The enthalpy change of the reaction $(A_2 + B_2 \rightarrow 2AB)$ in the presence of a catalyst will be (in $kJ \, mol^{-1}$)

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