Which of the following values of heat of formation indicates that the product is least stable in $kcal$?

The standard enthalpy of atomization of ethane according to the equation $C_2H_{6(g)} \rightarrow 2C_{(g)} + 6H_{(g)}$ is $622 \ kJ \ mol^{-1}$. If the standard mean $C-H$ bond dissociation enthalpy is $90 \ kJ \ mol^{-1}$,the standard mean dissociation enthalpy of the $C-C$ bond (in $kJ \ mol^{-1}$) is:

Given the bond energies of $N \equiv N$,$H - H$ and $N - H$ bonds are $945$,$436$ and $391 \ kJ \cdot mol^{-1}$ respectively,the enthalpy of the following reaction $N_{2(g)} + 3H_{2(g)} \to 2NH_{3(g)}$ is ...... $kJ$.

Calculate the $\Delta_fH^{\circ}$ of $N_2H_{4(g)}$ given the following bond energies:
$B.E.(N-N) = 159 \ kJ \ mol^{-1}$
$B.E.(H-H) = 436 \ kJ \ mol^{-1}$
$B.E.(N \equiv N) = 941 \ kJ \ mol^{-1}$
$B.E.(N-H) = 398 \ kJ \ mol^{-1}$

One mole of ethanol $(l)$ was completely burnt in oxygen to form $CO_{2(g)}$ and $H_2O_{(l)}$. What is the $\Delta_r H^{\ominus}$ (in $kJ \ mol^{-1}$) for this reaction?
(The standard enthalpy of formation $(\Delta_f H^{\ominus})$ of $C_2H_5OH_{(l)}$,$CO_{2(g)}$ and $H_2O_{(l)}$ is respectively $-277, -393$ and $-286 \ kJ \ mol^{-1}$.)

Calculate the heat change for the reaction $4NH_3(g) + 3O_2(g) \rightarrow 2N_2(g) + 6H_2O(l)$ in $kJ$. The enthalpies of formation of $NH_3(g)$ and $H_2O(l)$ at $298 \ K$ are $-46.0 \ kJ \ mol^{-1}$ and $-286.0 \ kJ \ mol^{-1}$ respectively.