Which of the following will not produce a precipitate with $AgNO_3$ solution?

$A$ white sodium salt dissolves readily in water to give a solution which is neutral to litmus. When silver nitrate solution is added to the solution,a white precipitate is formed which does not dissolve in dilute nitric acid. The anion could be

$A$ substance reacts with dilute $H_2SO_4$ to release a colorless gas,which turns baryta water $[Ba(OH)_2]$ turbid and decolorizes an acidic solution of dichromate. The presence of which of the following is indicated by this reaction?

$A$ salt,which on heating with conc. $H_2SO_4$ gives violet vapours,is

Assertion $(A) :- Fe^{+3}$ is not used in the brown ring test for $NO_3^{-}$.
Reason $(R) :-$ Reduction of $NO_3^{-}$ takes place during the test.

The reagent$(s)$ that can selectively precipitate $S^{2-}$ from a mixture of $S^{2-}$ and $SO_4^{2-}$ in aqueous solution is(are):
$(A)$ $CuCl_2$
$(B)$ $BaCl_2$
$(C)$ $Pb(CH_3COO)_2$
$(D)$ $Na_2[Fe(CN)_5NO]$