Which one of the following compounds will give an enantiomeric pair on treatment with $HOH$?

  • A
    $C_6H_5-C(C_2H_5)_2-I$
  • B
    $CH_3-C(CH_3)(C_2H_5)-Br$
  • C
    $C_6H_5-CH(D)-Br$
  • D
    $C_2H_5-C(C_2H_5)(CH_3)-Br$

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Haloalkanes react with $KCN$ to form alkyl cyanides as the main product,while $AgCN$ forms isocyanides as the chief product. Explain.

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Given below are two statements:
Statement $I$: $(Et)_2N-CH_2CH_2Cl$ will undergo alkaline hydrolysis at a faster rate than $(Et)_2CH-CH_2CH_2Cl$.
Statement $II$: Intramolecular substitution takes place first by involving the lone pair of electrons on nitrogen.
In the light of the above statements,choose the most appropriate answer from the options given below:

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