Which one of the following gases converts haemoglobin into carboxyhaemoglobin?

Which of the following practices will not come under green chemistry?
$1$. Using soaps made of vegetable oils instead of synthetic detergents,whenever possible.
$2$. Using $H_2O$ for bleaching purposes instead of chlorine-based bleaching agents.
$3$. Using liquefied $CO_2$ for dry cleaning clothes and laundry.
$4$. Using plastic cans for neatly storing substances.

Which of the following statements are correct?
a) $F^{-}$ ion concentration above $2 \ ppm$ causes brown mottling of teeth
b) The maximum limit of nitrate in drinking water is $400 \ ppm$
c) Depletion of ozone layer leads to cataract and skin cancer
d) The irritant red haze in the traffic is due to oxides of sulphur

Recent reports of acid rain in industrial cities are due to the effect of atmospheric pollution by

The ozone layer forms naturally by

The incorrect statement from the following is: