Which one of the following graphs is not applicable for a $1^{st}$ order reaction $(R \rightarrow P)$?

$A_{(g)} \xrightarrow{\Delta} P_{(g)} + Q_{(g)} + R_{(g)}$ follows first-order kinetics with a half-life of $69.3 \ s$ at $500^{\circ}C$. Starting from the gas '$A$' enclosed in a container at $500^{\circ}C$ and at a pressure of $0.4 \ atm$,the total pressure of the system after $230 \ s$ will be (in $atm$)

For a first order reaction,the initial concentration of a reactant is $0.05 \ M$. After $45 \ minutes$,it is decreased by $0.015 \ M$. Calculate the half-life period $(t_{1/2})$ (in $min$)?

$A$ flask contains a mixture of compounds $A$ and $B.$ Both compounds decompose by first-order kinetics. The half-lives for $A$ and $B$ are $300 \ s$ and $180 \ s,$ respectively. If the concentrations of $A$ and $B$ are equal initially,the time required for the concentration of $A$ to be four times that of $B$ (in $s$): (Use $\ln 2 = 0.693$)

Which of the following is a correct statement for a first-order reaction?

For a $1^{st}$ order reaction $R \rightarrow P$, the concentration of reactant $R$ changes from $0.1 \text{ M}$ to $0.025 \text{ M}$ in $40 \text{ minutes}$. The rate of reaction when the concentration of $R$ is $0.01 \text{ M}$ is