Which one of the following has a potential more than zero?

  • A
    $Pt, \frac{1}{2} H_{2}(1 \ atm) \mid HCl(2 \ M)$
  • B
    $Pt, \frac{1}{2} H_{2}(1 \ atm) \mid HCl(0.1 \ M)$
  • C
    $Pt, \frac{1}{2} H_{2}(1 \ atm) \mid HCl(0.5 \ M)$
  • D
    $Pt, \frac{1}{2} H_{2}(1 \ atm) \mid HCl(1 \ M)$

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The electrode potential of a chlorine electrode is maximum when the concentration of chloride ion in the solution (in $mol \ L^{-1}$) is $X$. What is the value of $X$?

Calculate the electrode potential at $298 \; K$ for $Zn|Zn^{2+}$ electrode in which the activity of zinc ions is $0.001 \; M$ and $E^o_{Zn^{2+}/Zn}$ is $-0.76 \; V$. (in $; V$)

The electrode potential of the following half cell at $298 \ K$ is given by the cell reaction:
$X | X^{2+}(0.001 \ M) || Y^{2+}(0.01 \ M) | Y$
The cell potential is $....... \times 10^{-2} \ V$ (Nearest integer).
Given: $E^0_{X^{2+} | X} = -2.36 \ V$,$E^0_{Y^{2+} | Y} = +0.36 \ V$,$\frac{2.303 \ RT}{F} = 0.06 \ V$.

Consider the cell at $25^{\circ} C$:
$Zn | Zn^{2+}_{(aq)} (1 \ M) || Fe^{3+}_{(aq)}, Fe^{2+}_{(aq)} | Pt_{(s)}$
The fraction of total iron present as $Fe^{3+}$ ion at the cell potential of $1.500 \ V$ is $X \times 10^{-2}$. The value of $X$ is $.....$ (Nearest integer).
(Given $E^{0}_{Fe^{3+} / Fe^{2+}} = 0.77 \ V, E^{0}_{Zn^{2+} / Zn} = -0.76 \ V$)

The standard $e.m.f.$ of a cell involving a one-electron change is found to be $0.591 \ V$ at $25^{\circ} C$. What is the equilibrium constant for the reaction? $(F = 96500 \ C \ mol^{-1}; R = 8.314 \ J \ K^{-1} \ mol^{-1})$

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