Which one of the following statements is correct for a reversible reaction? $A$ catalyst

At $T$ $(K)$,$K_c$ for the dissociation of $PCl_5$ is $2 \times 10^{-2} \ mol \ L^{-1}$. The number of moles of $PCl_5$ that must be taken in a $1.0 \ L$ flask at the same temperature to get $0.2 \ mol$ of chlorine at equilibrium is:

Consider the following reaction equilibrium:
$N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$
Initially,$1 \ mol$ of $N_2$ and $3 \ mol$ of $H_2$ are taken in a $2 \ L$ flask. At equilibrium,if the number of moles of $N_2$ is $0.6$,what is the total number of moles of all gases present in the flask?

The partial pressures of an equilibrium mixture of $H_2$,$N_2$,and $NH_3$ are $2 \, atm$,$1 \, atm$,and $3 \, atm$ respectively. If the value of $K_P$ for the reaction $N_2 + 3H_2 \rightleftharpoons 2NH_3$ at $725 \, K$ is $4.28 \times 10^{-5} \, atm^{-2}$,in which direction will the reaction proceed?

Solid $KClO_3$ is taken in a container maintained at a constant pressure of $1 \ atm$. Upon heating,the following equilibrium is obtained:
$2KClO_{3(s)} \rightleftharpoons 2KCl_{(s)} + 3O_{2(g)}$
If $\Delta H^o = 25 \ kcal/mol$ and $\Delta S^o = 50 \ cal/K$,at what temperature will equilibrium be established in the container? (Ignore variation of $\Delta H^o$ and $\Delta S^o$ with temperature.) $......K$

For the reaction $A + B \rightleftharpoons C + D$ at $250^\circ C$ in a $1 \ L$ vessel,the initial concentration of $A$ is $3$ and $B$ is $n$. If the equilibrium concentration of $C$ is equal to the equilibrium concentration of $B$,what is the equilibrium concentration of $D$?