Which one of the following would produce maximum elevation in boiling point?

Boiling point of water at $750 \, mm \, Hg$ is $99.63^{\circ} \, C$. How much sucrose is to be added to $500 \, g$ of water such that it boils at $100^{\circ} \, C$?

The elevation in boiling point of a $0.25 \ molal$ aqueous solution of a substance is $(K_b = 0.52 \ K \ kg \ mol^{-1})$. (in $K$)

An aqueous dilute solution containing non-volatile solute boils at $100.52^{\circ} C$. What is the molality of the solution (in $m$)? ($K_b = 0.52 \ K \ kg \ mol^{-1}$, boiling temperature of water $= 100^{\circ} C$)

When a substance is dissolved in a solvent,the vapour pressure of the solvent is decreased. This results in:

The molal boiling point constant for water is $0.513 \, ^oC \, kg \, mol^{-1}$. When $0.1 \, mol$ of sugar is dissolved in $200 \, mL$ of water,the solution boils under a pressure of one atmosphere at ......... $^oC$.