Which of the following is the correct equation representing the change in molar conductivity with respect to concentration for a weak electrolyte,where the symbols carry their usual meaning?

  • A
    $\Lambda_{m}^2 C + K_{a} \Lambda_{m} - K_{a} \Lambda_{m}^{\circ} = 0$
  • B
    $\Lambda_{m} - \Lambda_{m}^{\circ} + AC^{\frac{1}{2}} = 0$
  • C
    $\Lambda_{m} - \Lambda_{m}^{\circ} - AC^{\frac{1}{2}} = 0$
  • D
    $\Lambda_{m}^2 C + K_{a} \Lambda_{m} \Lambda_{m}^{\circ} - K_{a} (\Lambda_{m}^{\circ})^2 = 0$

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At $298 \text{ K}$, the specific conductance $(\kappa)$ of a $0.0020 \text{ M } NaCl$ solution is $2.50 \times 10^{-4} \text{ S cm}^{-1}$. Calculate the molar conductivity $(\Lambda_m)$ of the solution in $\text{S cm}^2 \text{mol}^{-1}$.

Given below are two statements $:$
Statement $I :$ Mohr's salt is composed of only three types of ions$-$ferrous,ammonium and sulphate.
Statement $II :$ If the molar conductance at infinite dilution of ferrous,ammonium and sulphate ions are $x_1, x_2$ and $x_3 \ S \ cm^2 \ mol^{-1}$,respectively then the molar conductance for Mohr's salt solution at infinite dilution would be given by $x_1+x_2+2 x_3$
In the light of the given statements,choose the correct answer from the options given below $:$

What is the effect of dilution on the equivalent conductivity of a strong electrolyte?

The unit of equivalent conductivity is

For a strong electrolyte, $\Lambda_{m}$ increases slowly with dilution and can be represented by the equation $\Lambda_{m} = \Lambda_{m}^{\circ} - Ac^{1/2}$. Molar conductivity values of a solution of strong electrolyte $AB$ at $18^{\circ} C$ are given below:
$c \ [mol \ L^{-1}]$$0.04$$0.09$$0.16$$0.25$
$\Lambda_{m} \ [S \ cm^2 \ mol^{-1}]$$96.1$$95.7$$95.3$$94.9$
The value of constant $A$ based on the above data [in $S \ cm^2 \ mol^{-1} / (mol \ L^{-1})^{1/2}$] is . . . . . . .

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